Temperature is just do to the amount of heat energy that a group of molecules have, so if you could concentrate the light of the Sun so that it was more intense than at the surface the temperature one could attain would be even higher. I was in bed and being very loose in my terminology. For a perfect black body at Earth's position the temperature would be about 0 C in fact it would be:
"An ideal thermally conductive
blackbody at the same distance from the Sun as Earth would have a temperature of about 5.3 °C (41.5 °F). However, because Earth reflects about 30%
[17][18] of the incoming sunlight, this idealized planet's
effective temperature (the temperature of a blackbody that would emit the same amount of radiation) would be about −18 °C (0 °F).
[19][20] The surface temperature of this hypothetical planet is 33 °C (59 °F) below Earth's actual surface temperature of approximately 14 °C (57 °F).
[21] The greenhouse effect is the contribution of greenhouse gases to this difference"
Greenhouse effect - Wikipedia
Black body radiation has been understood since the 1800's. The Earth is warmer than a perfect black body and even warmer still than a body with Earth's albedo "should" have. The clear excess temperature of the Earth is what led to the Greenhouse effect. Okay far enough off of topic.
One could concentrate the energy but only to a point. If one uses molten sodium rather than water one would still have the limitation of not being able to harvest more energy than the metal conduits of the molten sodium could handle. Still it would be interesting to get some proposed figures. What I worry about is trying to radiate off heat after it has been harvested.